​​​​​​​June 2020, Vol. 5, No. 7, pp. 182-190. 

​​Calcium Carbonate Synthesis, Optimization and Characterization from Egg Shell

Temesgen Abeto Amibo¹*, Abreham Bekele Bayu²
¹School of Chemical Engineering, Jimma Institute of Technology, Jimma University, Jimma, Ethiopia.
²School of Chemical Engineering, Jimma Institute of Technology, Jimma University, Jimma, Ethiopia.

​​*Corresponding author’s e-mail: temeabeto@gmail.com

Abstract

In this study, to determine the calcium carbonate availability in eggshells waste and factors those affect its extraction. The parameters like temperature, the size of the eggshell powder and the amount of solvent have highly affected the yield of calcium carbonate obtained from eggshells. The calcium carbonate was synthesized with the temperatures of 65, 100, 150, 200 and 234°C. The eggshell powder size was 29, 50, 80, 110, and 130 μm. The volume of water to mass of eggshell ratio was (ml/g) 26, 30, 35, 40 and 43. The boiling process for 30 min of eggshell kills any microbial growth on the surface. The grinding, drying and separating process was carried out for 25, 30 and 10 min respectively. The obtained results indicated that the addition of temperature led to slightly increase calcium carbonate yield when the diameter is 29 μm, the calcium carbonate yield increases highly until the temperature reaches to 150 °C for 130 μm diameter then declines and finally the calcium carbonate yield decreases as the temperature increases for the diameter of above 125 μm. The maximum yield is 54.0%, obtained at the temperature of 200°C, the diameter of 110 μm and a ratio of 40 ml/g.

Keywords: Calcium carbonate; Eggshell; Environment; Optimization; Synthesis; Yield.

References

  1. Nowak-Sliwinska P, Alitalo K, Allen E, Anisimov A, Aplin AC, Auerbach R, Augustin HG, Bates DO, van Beijnum JR, Bender RHF, Bergers G. Consensus guidelines for the use and interpretation of angiogenesis assays. Angiogenesis 2018; 21(3):425-532.
  2. Stadelman WJ, Newkirk D, Newby L. Egg science and technology. CRC Press, 2017.
  3. Ray S, Barman AK, Roy PK, Singh BK. Chicken eggshell powder as dietary calcium source in chocolate cakes. The Pharma Innovation. 2017;1;6(9, Part A):1.
  4. Farhadi-Khouzani M. Study of Structures and Crystallization Behavior of Amorphous Calcium Carbonate (ACC) and its Application in Bio-inspired Materials (Doctoral dissertation).
  5. Erdogan N, Eken HA. Precipitated calcium carbonate production, synthesis and properties. Physicochemical Problems of Mineral Processing. 2017;53.
  6. Miculescu F, Mocanu AC, Maidaniuc A, Dascalu CA, Miculescu M, Voicu S, Ciocoiu RC. Biomimetic calcium phosphates derived from marine and land bioresources. Hydroxyapatite—Advances in Composite Nanomaterials, Biomedical Applications and Its Technological Facets; InTechOpen: London, UK. 2018;14:89-108.
  7. Murakami FS, Rodrigues PO, Campos CM, Silva MA. Physicochemical study of CaCO3 from egg shells. Food Science and Technology. 2007;27(3):658-62.
  8. Rasheed SP, Shivashankar M, Dev S, Azeem AK. Treatment of biowaste to pharmaceutical excipient. Materials Today: Proceedings. 2019;15:316-22.
  9. Morse JW, Arvidson RS, Lüttge A. Calcium carbonate formation and dissolution. Chemical Reviews. 2007;107(2):342-81.
  10. Cree D, Rutter A. Sustainable bio-inspired limestone eggshell powder for potential industrialized applications. ACS Sustainable Chemistry & Engineering. 2015;3(5):941-9.
  11. Cheremisinoff NP. Handbook of solid waste management and waste minimization technologies. Butterworth-Heinemann; 2003.
  12. Yusuf AA. Utilization of organic and inorganic calcium and dehydrated food waste in    improving egg production and egg quality of village chicken layers, Maters Thesis, 2016.
  13. Zebire DA, Ayele T, Ayana M. Characterizing soils and the enduring nature of land uses around the Lake Chamo Basin in South-West Ethiopia. Journal of Ecology and Environment 2019;43(1):15.

ISSN 2456-0235

International Journal of Modern Science and Technology

INDEXED IN