June 2019, Vol. 4, No. 6, pp 138-147.
Comparative Study of Biodiesels Produced from Waste of Beef Tallow, Avocado Pear, Watermelon and Desert Date as Alternative Source of Energy
Agbaye Gabriel¹*, Ogo Ogo², Inalegwu Bawa¹
¹Department of Biochemistry, University of Agriculture, Makurdi, Nigeria.
²Department of Biochemistry, Benue State University, Makurdi, Nigeria.
*Corresponding author’s e-mail: agbaye.gabriel@gmail.com
Abstract
Biodiesel is fossil fuel substitute in which it quantity continually decreases due to increasing demand. This work entails the production of biodiesel from waste of beef tallow fat, Avocado pulp, watermelon (Citrullus lanatus) oil and desert date (Balanite aegyptiaca) kernel. Oils from plant materials were extracted with N-hexane using Soxhlet extractor. Biodiesel or fatty acid methyl esters (FAME) were produced from these four feedstocks via transestrification with NaOH as catalytst. Results show percentage biodiesel yield of 87.40%, 81.92%, 57.24% and 92.03% for beef tallow, avocado seed pulp, watermelon seeds and balanite kernel oils respectively and this indicate that they are viable feedstock for biodiesel production. Results of the physico-chemical evaluation of their individual biodiesels showed viscosities (4.92, 5.02, 3.70, 5.42 mm2/s), densities( 0.87, 0.93, 0.86, 1.33 g/cm3), acid value ( 0.28, 0.84, 3.09, 0.56 mg KOH/g), free fatty acid (0.14, 0.42, 1.54, 0.24 mg/g), iodine value ( 45.04, 38.7, 0.89, 0 gI2/100g), flash point (154, 172, 102, 172 0C) and cloud point (-8, -5, -2, -13 0C) for beef tallow, avocado seed pulp, watermelon seeds and balanite kernel biodiesels respectively. Not all fuel samples are consistent with ASTM D6751 standard limit. Thus, B20 blends were made and evaluated for major fuel parameters. Comparison of the four B20 blends results show that all four biodiesel blends were within regulatory standard limits. The B20 blends of balanite and watermelon have advantage of improved diesel characteristics thus can be used in place of fossil based diesel.
Keywords: Biodiesel; Feedstocks; Transesterification; Soxhlet; Beef tallow.
References
- Knothe G, Sharp CA, Ryan TW. Exhaust Emissions of Biodiesel, Petrodiesel, Neat Methyl Esters, and Alkanes in a New Technology Engine. Energy and Fuels 2006;20:403-8.
- Romano SD, González SE, Laborde MA. Biodiesel. In: Combustibles a. Alternativos, (2nd eds.). Ediciones Cooperativas, Buenos Aires. 2006.
- Janaun J, Ellis N. Perspectives on biodiesel as a sustainable fuel. Renewable and Sustainable Energy Reviews 2010;14:1312-20.
- Tafere A. Production and characterization of biodiesel from Avocado peel oil (APO). M.Sc. Thesis, Department of chemical Engineering, Addis Ababa Institute of Technology, Addis Ababa. 2018.
- Okia CA. Nutritional value of commonly consumed desert date tree products. African Crop Science Journal 2013;21: 657-67.
- Deshmukh SJ, Bhyyar LB. Transesterified Hhingain (Balanites) Oil as a Fuel for Compression Ignition Engines. Biomass and Bioenergy 2009;33:108-12.
- Mansur A, Riskuwa F, Kasimu AS, Shehu U. Analysis of essential oil from watermelon seeds. SosPoly Journal of Science and Agriculture 2017;2:1-7.
- Tomasevic AV, Marinkovic SS. Methanolysis of used frying oils. Fuel Process Technol 2003;81:1-6
- Kaisan MU, Anafi FO, Nuszkwoski J, Kulla DM, Umaru S. Cold flow properties and viscosity of biodiesel from cotton, jatropha and neem binary and multi-blends with diesel. African Journal of Renewable Alternative Energy 2017; 1:80-9.
- Ogunwole O. Production of Biodiesel from Jatropha Oil. Research Journal of Chemical Sciences 2012;2:30-3.
- Babagana G, Shittu B, Idris B. Characterization and composition of Balanite aegyptiaca seed oil and its potential as biodiesel feedstock in Nigeria. Journal of applied phyto-technology environmental sanitation 2012; 1:12-6.
- Omujal F. Post-harvest handling practices and physicochemical characteristics of shea butter in Uganda. M.Sc. Thesis, Department of Chemistry, Makerere University, Kampala. 2008.
- American Society for Testing and Materials (ASTM). Standard Specification for Biodiesel Fuel (B100) Blend Stock for Distillate Fuels. ASTM International. 2003.
- EN 14214 Automotive Fuels-Fatty Acid Methyl Esters (FAME) for Diesel Engines - Requirements and Test Methods. 2003.
- Devine J, William PN. The Chemistry and Technology of Edible Oils and Fats London, Pergamon Press, 1961.
- Gandure J, Ketlogetswe C, Jonas M. Production, Composition and Fuel Properties of Tallow Biodiesel: A Case of Botswana. Energy and Power Engineering 2017;9:355-65. https://doi.org/10.4236/epe..97024
- Kaisan MU, Anafi FO, Nuszkwoski J, Kulla DM, Umaru S. Cold flow properties and viscosity of biodiesel from cotton, jatropha and neem binary and multi-blends with diesel. African Journal of Renewable Alternative Energy 2017; 1:80-9.
- Gunstone FD. The chemistry of oils and Fats: Sources, composition, properties and uses. London: Blackwell Publishing Ltd. 1994.
- Omotoso M A, Ayodele MJ, Akintudire AO. Comparative study of the properties of biodiesel prepared from jatropha curcas oil and palm oil. Global Research Journals 2011;1:1-13.
- Kaisan MU, Anafi FO, Nuszkwoski J, Kulla DM, Umaru S. Cold flow properties and viscosity of biodiesel from cotton, jatropha and neem binary and multi-blends with diesel. African Journal of Renewable Alternative Energy. 2017;1:80-9.
- Mata T, Mendes A, Caetano N, Martins A. Properties and Sustainability of Biodiesel from Animal Fats and Fish Oil. Chemical Engineering Transactions 2014;38:175-80
- Manji A, Sarah E, Modibbo U. Studies on the potentials of Balanites aegyptiaca seed oil as raw material for the production of liquid cleansing agents. International Journal of Physical Sciences 2013;8:1655-60.
- Sara ME. Physicochemical Properties of Balanites aegyptiaca (Laloub) Seed Oil. M.Sc. Thesis, Department of food science and technology, Sudan University of Science and Technology, Khartoum. 2015.
- Tsegay H. Determination of oil and biodiesel content, physicochemical properties of the oil extracted from avocado seed (Persea Americana) grown in Wonago and Dilla (gedeo zone). Southern Ethiopia Hiwot / Chemistry International 2017;3:311-19.
- Knothe G. Biodiesel and Renewable diesel: A comparison. Progress in Energy and Combustion Science 2010;36:364-73.
- Eman N, Ali Cadence IT. Characterization of biodiesel produced from palm oil via base catalyzed transesterification. Procedia Engineering 2012;53:7-12.
- Akpan UG, Jimoh A, Mohammed AD. Extraction, characterization and modification of castor seed oil. Journal Association of Oil Chemists 2008;72:1155-60.